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The crystal structure of superconducting LuNi 2 B 2 C and the related phase LuNiBC

Summary

This article discusses the crystal structure of two new phases found in the Lu–Ni–B–C system: LuNi 2 B 2 C and LuNiBC. LuNi 2 B 2 C is a superconductor with a transition temperature of 16.6 K, and LuNiBC is a closely related, non-superconducting phase. The superconductor is a variant on the layered ThCr 2 Si 2 -type structure, while LuNiBC is derived from LuNi 2 B 2 C by adding a layer of Lu–C, creating a NaCl-type intergrowth. The article suggests that a new homologous series of intermetallic phases could be derived from these two structures.

Q&As

What is the formula of the superconducting phase in the Ln–Tr–B–C system?
The formula of the superconducting phase in the Ln–Tr–B–C system is LnNi 2 B 2 C.

What is the transition temperature of the superconducting phase LuNi 2 B 2 C?
The transition temperature of the superconducting phase LuNi 2 B 2 C is 16.6 K.

What is the derived non-superconducting phase from LuNi 2 B 2 C?
The derived non-superconducting phase from LuNi 2 B 2 C is LuNiBC.

What is the structure of the superconductor?
The structure of the superconductor is a variant on the layered ThCr 2 Si 2 -type structure.

What new homologous series of intermetallic phases may be derivable from the structures of LuNi 2 B 2 C and LuNiBC?
The new homologous series of intermetallic phases that may be derivable from the structures of LuNi 2 B 2 C and LuNiBC is a series of intermetallic phases derived from the simple building principles of these two structures.

AI Comments

👍 This article is a comprehensive review of the crystal structure of superconducting LuNi 2 B 2 C and the related phase LuNiBC, providing readers with a better understanding of the properties of these compounds.

👎 This article is lacking in detail and does not provide enough information for readers to understand the complex quaternary boro-carbides described in the article.

AI Discussion

Me: The article is about the crystal structure of superconducting LuNi 2 B 2 C and the related phase LuNiBC. It was published in 1994.

Friend: Interesting. What are the implications of the article?

Me: Well, the article suggests that there is a homologous series of intermetallic phases that can be derived from the two structures described in the article. It also suggests that understanding these structures could lead to further advancements in superconductivity research. Additionally, the article could be used to explore the effects of high pressure on the critical temperature and other thermodynamic properties of superconductors.

Action items

Technical terms

Superconducting
A phenomenon in which electrical current can flow without resistance in certain materials when cooled below a certain temperature.
Transition temperature (Tc)
The temperature at which a material changes from a superconducting to a non-superconducting state.
Lanthanide element (Y, Ho–Lu)
A series of elements in the periodic table, ranging from atomic number 57 (lanthanum) to atomic number 71 (lutetium).
Intermetallic compound
A compound composed of two or more metallic elements.
Ternary carbides and borides
Compounds composed of three elements, one of which is carbon or boron.
Quaternary boro-carbides
Compounds composed of four elements, one of which is carbon or boron.
ThCr2Si2-type structure
A type of crystal structure in which the atoms are arranged in a layered pattern.
NaCl-type intergrowth
A type of crystal structure in which the atoms are arranged in a cubic lattice.
Homologous series
A series of compounds with similar chemical and physical properties.

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